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Ammonium chloride is an inorganic compound with the formula NH4Cl and a white crystalline salt that is highly soluble in water. Solutions of ammonium chloride are mildly acidic. Sal ammoniac is a name of the natural, mineralogical form of ammonium chloride. The mineral is commonly formed on burning coal dumps from condensation of coal-derived gases. It is also found around some types of volcanic vents. It is mainly used as fertilizer and a flavouring agent in some types of liquorice. It is the product from the reaction of hydrochloric acid and ammonia.

It is a product of the Solvay process used to produce sodium carbonate:[3]

In addition to being the principal method for the manufacture of ammonium chloride, that method is used to minimize ammonia release in some industrial operations.

Ammonium chloride is prepared commercially by combining ammonia (NH3) with either hydrogen chloride (gas) or hydrochloric acid (water solution):[3]

Ammonium chloride occurs naturally in volcanic regions, forming on volcanic rocks near fume-releasing vents (fumaroles). The crystals deposit directly from the gaseous state and tend to be short-lived, as they dissolve easily in water.[11]

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